By Prof. Armin de Meijere (auth.)
Carbon wealthy Compounds are outlined right here as carbon skeletons with a carbon to hydrogen ratio of 1:(=<1) consisting of all-carbon compounds (i.e. carbon allotropes). the present quantity covers glossy equipment for the coaching and transformation of polycyclic fragrant compounds together with substructures of C60-fullerene and novel hugely advanced cyclophanes. A graph theoretical therapy offers a substitution rule, permitting the outline of already current constructions and in addition the definition of latest demanding artificial ambitions. within the moment a part of this quantity, the synthesis and particular chemistry of oligocyclic compounds together with 5- and 6-membered jewelry, so-called centro-polyhydrindanes in addition to oligoquinanes, specifically hugely unsaturated ones, are discussed.
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50 52 53 55 . . . 56 . . . 60 . . . 60 . . . . . . . . . . 62 63 63 64 . . . 65 Topics in Current Chemistry, Vol. 196 © Springer Verlag Berlin Heidelberg 1998 46 S. Hagen · H. 5 Oxazoline Coupling (Meyer’s Coupling) . . . . . Transition Metal Catalyzed Grignard Coupling Reactions Suzuki and Stille Coupling . . . . . . . . . Silicon Reagents . . . . . . . . . . . . Heck-Type Reactions . . . . . . . . . . 5 [2 + 2 + 2] Cyclotrimerization Reactions of Alkynes and Arynes .
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G. the catalytic hydrocracking of petroleum to produce gasoline, pyrolytic processes used in the formation of lower olefins and soot or the carbonization of coal in coke production . The structures of benzene and polycyclic aromatic hydrocarbons (PAHs) can be found in many industrial products such as polymers , specialized dyes and luminescence materials , liquid crystals and other mesogenic materials . Furthermore, the intrinsic (electronic) properties of aromatic compounds promoted their use in the design of organic conductors , solar cells , photo- and electroluminescent devices [3, 7], optically active polymers , non-linear optical (NLO) materials , and in many other fields of research.
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